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The bifunctional alcohol 1,4-butanediol is a versatile intermediate for the chemical industry. It reacts with dicarboxylic acids to yield polyesters, with diisocyanates to yield polyurethanes, and with phosgene to yield chloroformates. The main applications for butanediol are the production of cellular plastics, thermoplastic polyesters, hot-melt adhesives and plasticizers.

In the textile industry, 1,4-butanediol is an additive in sizes and finishing baths. Similar to glycerol, it acts as a plasticizer for water-soluble binders. Plasticized products are less tacky in a humid atmosphere than those treated with glycerol because 1,4-butanediol is not as hygroscopic.

Applications

The most important fields of application for 1,4-butanediol are the manufacture of :
Polyurethanes
Polyurethanes offer more opportunities for attaching monomers than other plastics and are, thus, suitable for numerous applications. The most important fields of application are soft and rigid foams, microcellular elastomers (soft integral skin foams), laminates, surface coatings, adhesives, thermoplastics, fibers and dispersions.
 
Polybutyleneterephthalate
Polybutyleneterephthalate (PBT) is a thermoplastic polyester produced by the polycondensation of 1,4-butanediol with terephthalic acid or dimethylterephthalate. Preference is usually given to the reaction with the ester, which can be purified more easily to the degree required for polycondensation.

Some of the most important fields of applications for PBT are engineering materials, where PBT is able to compete with many engineering-grade thermoplastics and thermosetting plastics. PBT possesses superior outdoor performance, low water absorption, good dielectric properties, dimensional stability, satisfactory impact strength and the retention of these beneficial properties on exposure to fluctuating humidity or to chemicals. PBT is also used in hot-melt adhesives because of its high temperature stability, rapid crystallization, favorable flow at the processing temperature and good flexibility.
 
For further information on 1,4-butanediol, refer to the Technical Data Sheet, 1,4-butanediol Physical Properties Page or contact the appropriate regional Diols customer representative on the Customer Service Page.
 
     
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